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To do this start Deployment Tools Command Line as Administrator.

BootWim01

In this instance I was creating a x64 boot.wim and the command to run for this was COPYPE.CMD amd64 c:\WINPE64\

BootWim02

Here are all the commands for the different architectures:

COPYPE.CMD x86 c:\WINPE86\
COPYPE.CMD amd64 c:\WINPE64\
COPYPE.CMD arm c:\WINPEARM\

Execute the command.

BootWim03

Once run, navigate to the c:\WINPE64\media\sources folder and copy the boot.wim to a share for use with SCCM.

BootWim04

In the SCCM console go to the Software Library workspace. Open Operating Systems>Boot Images. Right click and choose ‘Add Boot Image’.